• 专利标题:   Reducing graphene oxide to coating lithium nickel cobalt manganese oxide cathode material by microwave-assisted synthesis involves performing microwave roasting of mixed powder in air atmosphere, heating, and cooling to room temperature.
  • 专利号:   CN113299891-A
  • 发明人:   LIU B, DONG E, JI H, ZHAO Y, GUO S
  • 专利权人:   UNIV KUNMING SCI TECHNOLOGY
  • 国际专利分类:   C01B032/198, H01M010/0525, H01M004/36, H01M004/485, H01M004/583, H01M004/62
  • 专利详细信息:   CN113299891-A 24 Aug 2021 H01M-004/36 202187 Pages: 8 Chinese
  • 申请详细信息:   CN113299891-A CN10555944 21 May 2021
  • 优先权号:   CN10555944

▎ 摘  要

NOVELTY - Reducing graphene oxide coating lithium nickel cobalt manganese oxide cathode material by microwave-assisted synthesis involves mixing uniformly lithium acetate dihydrate, manganese acetate tetrahydrate, nickel acetate tetrahydrate, and cobalt acetate tetrahydrate, drying, grinding to obtain first mixed powder, performing microwave roasting the obtained mixed powder in air atmosphere at a temperature of 300-400 degrees C for 20-40 minutes, heating to a temperature of 850-950 degrees C for microwave roasting for 3-6 hours, cooling to room temperature, grinding, sieving to obtain LiNi1/3Co1/3Mn1/3O2 cathode material, adding graphene oxide an the obtained LiNi1/3Co1/3Mn1/3O2 cathode material to absolute ethanol, and stirring magnetically uniformly. USE - Method for reducing graphene oxide coating lithium nickel cobalt manganese oxide cathode material by microwave-assisted synthesis. ADVANTAGE - The method has promote the graphene oxide pyrolysis and high-temperature solid phase sintering, and significantly improves the electrochemical performance of the nickel-cobalt-manganese ternary lithium ion battery. DETAILED DESCRIPTION - Reducing graphene oxide coating lithium nickel cobalt manganese oxide cathode material by microwave-assisted synthesis involves mixing uniformly lithium acetate dihydrate, manganese acetate tetrahydrate, nickel acetate tetrahydrate, and cobalt acetate tetrahydrate, drying, grinding to obtain first mixed powder, performing microwave roasting the obtained mixed powder in air atmosphere at a temperature of 300-400 degrees C for 20-40 minutes, heating to a temperature of 850-950 degrees C for microwave roasting for 3-6 hours, cooling to room temperature, grinding, sieving to obtain LiNi1/3Co1/3Mn1/3O2 cathode material, adding graphene oxide an the obtained LiNi1/3Co1/3Mn1/3O2 cathode material to absolute ethanol, stirring magnetically uniformly, dispersing ultrasonically to obtain second mixed slurry, evaporating quickly the obtained second mixed slurry to dryness at a temperature of 100-120 degrees C, performing under microwave condition, raising the temperature at a constant speed to 300-400 degrees C and performing microwave thermal reduction for 20-40 minutes to obtain reduced graphene oxide coated LiNi1/3Co1/3Mn1/3O2 cathode material.