• 专利标题:   Preparation of reduced nanocomposite involves dispersing graphene oxide in water, adding solvent to dianhydride and diamine, reacting with neutralizing agent and aqueous graphene oxide, drying, thermally imidizing and reducing, and cooling.
  • 专利号:   CN103602065-A, CN103602065-B
  • 发明人:   AN F, LV C, ZHANG S, YUAN H
  • 专利权人:   INST COAL CHEM CHINESE ACAD SCI
  • 国际专利分类:   C08G073/10, C08J005/18, C08K003/04, C08K009/00, C08L079/08
  • 专利详细信息:   CN103602065-A 26 Feb 2014 C08L-079/08 201432 Pages: 9 Chinese
  • 申请详细信息:   CN103602065-A CN10596535 25 Nov 2013
  • 优先权号:   CN10596535

▎ 摘  要

NOVELTY - Preparation of reduced graphene and polyimide nanocomposite comprises adding graphene oxide to deionized water and ultrasonic dispersing for 60-180 minutes at under room temperature to obtain 0.5-5 mg/ml aqueous graphene oxide liquid; adding solvent to dianhydride and diamine, stirring under inert gas protection, reacting for 2-24 hours, adding diamine neutralizing agent, continuously reacting, stirring, adding to product in first step, and stirring for 30-60 minutes; vacuum drying; and carrying out thermal imidization and reduction, and naturally cooling. USE - Method for preparing reduced graphene and polyimide nanocomposite (claimed). DETAILED DESCRIPTION - Preparation of reduced graphene and polyimide nanocomposite comprises adding graphene oxide to deionized water and ultrasonic dispersing for 60-180 minutes at under room temperature, where ultrasonic powder is 100-150 W to obtain 0.5-5 mg/ml aqueous graphene oxide liquid; adding solvent to dianhydride and diamine, where total mass percentage is 11-24 wt.%, stirring 25 degrees C under inert gas protection, reacting for 2-24 hours, adding 2.2-2.4 times diamine neutralizing agent, continuously reacting for 0.5-2 hours, stirring, adding to product in first step, where mass ratio of graphene oxide dianhydride to diamine is 1:50-200, and stirring for 30-60 minutes; vacuum drying at 60-80 degrees C; and carrying out thermal imidization and reduction at 100 degrees C for 0.5-2 hours, 150 degrees C for 0.5-2 hours, 200 degrees C for 0.5-2 hours, 250 degrees C for 0.5-2 hours, and 300 degrees C for 0.5-2 hours, and naturally cooling.