• 专利标题:   Preparing dendritic composite nanowire three-dimensional electrode material useful for sewage treatment containing hexavalent chromium, comprises e.g. growing polypyrrole nanowires on three-dimensional anode, adding aniline to sulfuric acid, stirring, and reacting to obtain electrode material.
  • 专利号:   CN113443686-A, CN113443686-B
  • 发明人:   CHEN J, LIANG C, FAN C, QIU S
  • 专利权人:   UNIV JINAN
  • 国际专利分类:   C02F101/22, B82Y040/00, B82Y030/00, C08G073/06, C08G073/02, C02F001/461
  • 专利详细信息:   CN113443686-A 28 Sep 2021 C02F-001/461 202104 Chinese
  • 申请详细信息:   CN113443686-A CN10670446 17 Jun 2021
  • 优先权号:   S, WANG Y, LIU HCN10670446

▎ 摘  要

NOVELTY - Preparing dendritic composite nanowire three-dimensional electrode material comprises (1) growing polypyrrole nanowires on the three-dimensional anode to support the three-dimensional electrode material, (2) adding aniline to sulfuric acid, adding the polypyrrole nanowire-supported three-dimensional electrode material prepared in the step (1), uniformly stirring, and cooling the obtained solution to 4-5degrees Celsius, where the concentration of aniline in the solution is 100-200 mM, and (3) adding ammonium persulfate in sulfuric acid at 4-5degrees Celsius, immediately adding to the solution in the step (2) to obtain mixed solution after stirring for 30-35 seconds, stirring for 30-35 seconds, allowing to stand the reaction in environment of 4-5degrees Celsius for 24-25 hours to obtain dendritic polypyrrole (PPy)-polyaniline (PANI) composite nanowire three-dimensional electrode material. USE - The electrode material is useful for sewage treatment containing hexavalent chromium (claimed). ADVANTAGE - The electrode material: has larger specific surface area; provides more reactive sites; improves current efficiency and reduction efficiency; and is suitable for large-scale industrial chromium (VI) sewage treatment with high flux and high concentration. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for dendritic composite nanowire three-dimensional electrode material prepared by the preparation method.