• 专利标题:   New graphene adsorption multi-component chiral catalyst 2a/graphene useful in asymmetric hydrogenation of dehydrogenated amino acid derivatives.
  • 专利号:   CN110841720-A
  • 发明人:   HAO E, SU F, WANG Y, LI W, SHEN M, LI G, SHI L
  • 专利权人:   UNIV HENAN NORMAL
  • 国际专利分类:   B01J031/22, B01J031/24, C07B053/00, C07C231/12, C07C233/47
  • 专利详细信息:   CN110841720-A 28 Feb 2020 B01J-031/24 202030 Pages: 14 Chinese
  • 申请详细信息:   CN110841720-A CN11197783 29 Nov 2019
  • 优先权号:   CN11197783

▎ 摘  要

NOVELTY - Graphene adsorption multi-component chiral catalyst 2a/graphene compound (I) is new. USE - (I) is useful in asymmetric hydrogenation of dehydrogenated amino acid derivatives (claimed). ADVANTAGE - (I): exhibits excellent asymmetry induction effect, more than 99% conversion rate and 96% enantiomeric excess; can be recycled by simple filtration; and provides excellent reference for the development of other heterogeneous hybrid chiral catalysts based on asymmetric reactions with non-covalent interactions. DETAILED DESCRIPTION - Graphene adsorption multi-component chiral catalyst 2a/graphene compound of formula (I) is new. boxes = adsorption on graphene. INDEPENDENT CLAIMS are also included for: (1) preparation of (I); and (2) use of (I) in asymmetric hydrogenation of dehydrogenated amino acid derivatives.