• 专利标题:   Graphene-modified fluorine-containing lead dioxide electrode comprises titanium substrate, tin-antimony oxide substrate, alpha-lead dioxide intermediate layer and beta-lead dioxide active layer.
  • 专利号:   CN106868509-A, CN106868509-B
  • 发明人:   DUAN X, CHANG L, REN X, ZHAO X, TANG Q
  • 专利权人:   UNIV JILIN NORMAL, UNIV JILIN NORMAL
  • 国际专利分类:   C02F001/461, C02F101/30, C23C018/12, C23C028/04, C25D015/00, C25D003/02, C25D005/20
  • 专利详细信息:   CN106868509-A 20 Jun 2017 C23C-028/04 201750 Pages: 12 Chinese
  • 申请详细信息:   CN106868509-A CN10178144 23 Mar 2017
  • 优先权号:   CN10178144

▎ 摘  要

NOVELTY - Graphene-modified fluorine-containing lead dioxide electrode comprises titanium substrate, tin-antimony oxide substrate, alpha -lead dioxide intermediate layer and beta -lead dioxide active layer. The tin-antimony oxide substrate, alpha -lead dioxide intermediate layer and beta -lead dioxide active layer of electrode contain graphene. USE - Graphene-modified fluorine-containing lead dioxide electrode. ADVANTAGE - The electrode improves service life. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the preparation of graphene-modified fluorine-containing lead dioxide electrode comprising pretreating titanium matrix, coating liquid containing graphene on the surface of titanium substrate, drying at 120 degrees C for 10 minutes, calcining dried titanium substrate at 300 degrees C for 10 minutes, repeating 10 times, cooling naturally to room temperature, using electrode as anode and stainless steel plate as cathode, depositing electrostatically alpha -lead dioxide in 100 ml alkaline plating solution mixed with graphene at 40 degrees C for 0.5-2 hours, washing with deionized water, using electrode as anode and stainless steel plate as cathode, electrocoating beta -lead dioxide active layer in 100 ml acidic bath mixed with graphene at 65 degrees C for 0.5-2 hours and washing with deionized water.