• 专利标题:   New zirconium-metal-organic frameworks-reduced graphene oxide-silver phosphate visible light catalyst useful for: degradation of organic pollutant; and inactivation of bacteria and prepared by adding graphene oxide flakes into zirconium-metal-organic frameworks and silver phosphate nanoparticles.
  • 专利号:   CN113769788-A
  • 发明人:   NI L, WANG Y
  • 专利权人:   UNIV TONGJI
  • 国际专利分类:   B01J031/22, B01J031/26, B01J035/10, B01J037/03, B01J037/10, B01J037/16, C02F001/30, C02F001/50, C02F101/30, C02F101/34, C02F101/36, C02F101/38
  • 专利详细信息:   CN113769788-A 10 Dec 2021 B01J-031/22 202234 Chinese
  • 申请详细信息:   CN113769788-A CN10973165 24 Aug 2021
  • 优先权号:   CN10973165

▎ 摘  要

NOVELTY - Aerobic/anaerobic dual-purpose visible photocatalyst i.e. zirconium-metal-organic frameworks/reduced graphene oxide/silver phosphate visible light catalyst (I), is new. In visible light catalyst zirconium-metal-organic frameworks are wrapped by sheet-like reduced graphene oxide and silver phosphate nanoparticles are dispersed on the surface of zirconium-metal-organic frameworks/reduced graphene oxide to form a Z-type heterojunction; the conduction band edge potential of the visible photocatalyst is lower than the direct generation potential of O2- and valence band edge potential is higher than the direct generation potential of OH. USE - The visible photocatalyst is useful for: degradation of organic pollutant; and inactivation of bacteria (claimed). ADVANTAGE - The method: has simple operation, mild reaction conditions, short synthesis period and good repeatability; is suitable for large-scale mass production compared to other existing methods. The visible photocatalyst: has significant visible light photocatalytic activity; exhibits high photocatalytic efficiency in both aerobic and anaerobic states; and shows broad range of pollutant degradation and sterilization in the water environment. DETAILED DESCRIPTION - Aerobic/anaerobic dual-purpose visible photocatalyst i.e. zirconium-metal-organic frameworks/reduced graphene oxide/silver phosphate visible light catalyst of formula (I) (MOFs/rGO/AgPO4), is new. In visible light catalyst zirconium-metal-organic frameworks are wrapped by sheet-like reduced graphene oxide and silver phosphate nanoparticles are dispersed on the surface of zirconium-metal-organic frameworks/reduced graphene oxide to form a Z-type heterojunction; the conduction band edge potential of the visible photocatalyst is lower than the direct generation potential of O2- and valence band edge potential is higher than the direct generation potential of OH. An INDEPENDENT CLAIM is also included for preparation of (I).