• 专利标题:   Positive electrode material used in rechargeable magnesium battery, is polyimide/graphene composite.
  • 专利号:   CN111490233-A
  • 发明人:   JIN Z, WANG Y, XUE X, CHEN R
  • 专利权人:   UNIV NANJING, NANJING QINGHUI NEW ENERGY CO LTD, SUZHOU JINTAN NEW MATERIAL TECHNOLOGY CO, HAIAN MOXING NEW MATERIAL TECHNOLOGY CO
  • 国际专利分类:   H01M010/054, H01M004/36, H01M004/583, H01M004/60
  • 专利详细信息:   CN111490233-A 04 Aug 2020 H01M-004/36 202074 Pages: 6 Chinese
  • 申请详细信息:   CN111490233-A CN10075025 25 Jan 2019
  • 优先权号:   CN10075025

▎ 摘  要

NOVELTY - Positive electrode material is a polyimide/graphene composite. USE - The positive electrode material is useful in a rechargeable magnesium battery (claimed). ADVANTAGE - The positive electrode material avoids low rate performance and cycle reversibility caused by the dissolution of organic substances with redox activity in the electrolyte and conductivity difference and provides the assembled magnesium battery exhibiting excellent electrochemical magnesium storage performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing the positive electrode material involving (i) adding graphene into an N-methylpyrrolidone solution and performing an ultrasonic treatment to obtain a graphene dispersion liquid, (ii) adding 1,4,5,8-naphthalenetetracarboxylic dianhydride to the graphene dispersion liquid, adding p-phenylenediamine and refluxing for 5-10 hours under nitrogen protection, (iii) cooling to room temperature, filtering the product, washing with N-methyl-2-pyrrolidone and vacuum drying at 100-150 degrees C for 12-25 hours and (iv) finally, sintering at 300 degrees C for 6-10 hours under nitrogen atmosphere to yield the final product.