• 专利标题:   Preparing lithium-ion carbon cathode material, comprises e.g. dispersing graphene oxide in flask containing tetrahydrofuran, adding thionyl chloride, dispersing the solid sample in tetrahydrofuran, then adding the mixture of triethylamine and ethane thiol, filtering and washing with tetrahydrofuran.
  • 专利号:   CN114975949-A
  • 发明人:   AN B, LI L, LI J, LI Z, XU G, WANG K, WANG L, MO B, ZHOU W
  • 专利权人:   UNIV LIAONING SCI TECHNOLOGY, JIXI WEIDA NEW MATERIAL TECHNOLOGY CO
  • 国际专利分类:   H01M004/36, H01M004/48, H01M004/58
  • 专利详细信息:   CN114975949-A 30 Aug 2022 H01M-004/36 202286 Chinese
  • 申请详细信息:   CN114975949-A CN10663232 13 Jun 2022
  • 优先权号:   CN10663232

▎ 摘  要

NOVELTY - Preparing lithium-ion carbon cathode material, comprises (i) dispersing 300-500 mg graphene oxide in flask containing 30-50 ml of tetrahydrofuran, ultrasonically oscillating, adding 150-200 µl thionyl chloride, circulating for 1-3 hours at 45-50 ℃, filtering and repeatedly washing with tetrahydrofuran to obtain solid sample, (ii) dispersing the solid sample in tetrahydrofuran, then adding the mixture of triethylamine and ethane thiol of 6-14 times of the total amount of carboxy and hydroxy in graphene oxide, reacting for 4-6 hours under the temperature of 45-50 ℃, and (iii) after the reaction is completed, filtering and washing with tetrahydrofuran, drying at 80-120 ℃ under normal pressure for 10-14 hours to obtain sulfur-modified graphene by adding 6-14 times the molar ratio of reactants. USE - The method is useful for preparing lithium-ion carbon cathode materials. ADVANTAGE - The lithium-ion carbon cathode material improves specific capacity and cycle stability.