• 专利标题:   Multifunctional composite sulfur recycling catalyst comprises porous carrier, graphene, vanadium pentoxide, lanthanum oxide, rhenium oxide, cobalt and iron salt in ferric oxide.
  • 专利号:   CN108525672-A
  • 发明人:   CHEN J, CHEN L, DING J, DU C, ZHANG Q, DU J
  • 专利权人:   JIANGSU TIANDONG NEW MATERIALS TECHNOLOG
  • 国际专利分类:   B01J023/847, B01J035/10, B01J037/34, B01J037/08, B01J032/00, B01J023/06, C01B017/04
  • 专利详细信息:   CN108525672-A 14 Sep 2018 B01J-023/847 201870 Pages: 13 Chinese
  • 申请详细信息:   CN108525672-A CN10388589 26 Apr 2018
  • 优先权号:   CN10388589

▎ 摘  要

NOVELTY - Multifunctional composite sulfur recycling catalyst comprises 80-90 pts. wt. porous carrier with particle diameter of 600-1000 mu m, 6-15 pts. wt. graphene, 1.2-1.8 pts. wt. vanadium pentoxide, 0.1-0.3 pt. wt. lanthanum oxide, 0.2-0.3 pt. wt. rhenium oxide, 0.1-0.2 pt. wt. cobalt and 12-15 pts. wt. iron salt in ferric oxide. The porous carrier comprises 20-30 pts. wt. active alumina, 15-20 pts. wt. titanium dioxide, 30-40 pts. wt. silicon dioxide and 2-3 pts. wt. zinc oxide. The iron salt is ferric nitrate, ferric sulfate and/or ferrous sulfate. USE - Multifunctional composite sulfur recycling catalyst. ADVANTAGE - The catalyst has good Claus activity, organic sulfur hydrolysis activity, good antioxidation function, and uniform performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the catalyst comprising preparing raw materials; dissolving iron salt in deionized water to prepare iron salt solution; ultrasonically dispersing graphene in deionized water, adding porous carrier, and uniformly mixing; adding iron salt solution to mixed solution, sonicating, adding vanadium pentoxide, cerium oxide and cobalt oxide to prepare preliminary catalyst; evaporating and concentrating preliminary product under ultrasonic vibration conditions at 80-90 degrees C; and drying at 120-150 degrees Cfor 10-20 minutes, and drying at 500-530 degrees C for 2-4 hours.