• 专利标题:   Preparation of nitrogen-doped graphene-metal oxide nanocomposite material for use in e.g. lithium ion batteries, involves ultrasonically dispersing nitrogen-doped graphene in metal salt/organic solution and dripping deionized water.
  • 专利号:   CN106159228-A, CN106159228-B
  • 发明人:   LI Y, ZHU Z, HUANG G, JUNG Y, ZHANG H, ZHU J
  • 专利权人:   UNIV GUANGDONG TECHNOLOGY, UNIV GUANGDONG TECHNOLOGY
  • 国际专利分类:   B82Y030/00, H01G011/24, H01G011/36, H01G011/46, H01G011/86, H01M004/36, H01M004/48, H01M004/587
  • 专利详细信息:   CN106159228-A 23 Nov 2016 H01M-004/36 201719 Pages: 10 Chinese
  • 申请详细信息:   CN106159228-A CN10602035 26 Jul 2016
  • 优先权号:   CN10602035

▎ 摘  要

NOVELTY - Preparation of nitrogen-doped graphene-metal oxide nanocomposite material, involves (i) reacting graphene oxide or partially reduced graphene with nitrogen-enriched material, naturally cooling, suction-filtering, washing with deionized water and drying to obtain nitrogen-doped graphene, (ii) ultrasonically dispersing nitrogen-doped graphene in metal salt/organic solution, dripping deionized water to obtain homogeneous dispersion of mixture of metal salt and nitrogen-doped graphene, (iii) performing solvothermal reaction, cooling naturally, (iv) suction-filtering, washing and drying. USE - Preparation of nitrogen-doped graphene-metal oxide nanocomposite material for use in lithium ion batteries and super-capacitors. ADVANTAGE - The nitrogen-doped graphene-metal oxide nanocomposite material is prepared by a simple method at low cost. The nitrogen-doped graphene-metal oxide nanocomposite material has excellent operability and repeatability. The method solves the problem of non-uniformity of the particle size of the metal oxide particles on the surface of the graphene surface, and solves the problem of the nitrogen-doped content of the carrier in the composite material is not high. DETAILED DESCRIPTION - Preparation of nitrogen-doped graphene-metal oxide nanocomposite material, involves (i) reacting graphene oxide or partially reduced graphene with nitrogen-enriched material at 80-200 degrees C for 0.5-48 hours, naturally cooling, and carrying out suction filtration on the obtained product, washing with deionized water and drying to obtain nitrogen-doped graphene, (ii) ultrasonically dispersing the obtained nitrogen-doped graphene in metal salt/organic solution having a concentration of 0.002-1.0 mol/L, then dripping deionized water where dosage ratio of metal salt and deionized water is 1.0x 10-5-1.0x 10-2:1 mol/mL, and obtaining homogeneous dispersion of mixture of metal salt and nitrogen-doped graphene, (iii) transferring the dispersion to a reaction vessel, controlling the temperature to 80-240 degrees C, and maintaining for 0.1-72 hours, then carrying out solvothermal reaction, cooling naturally, (iv) carrying out suction filtration on the product obtained in step (iii), washing, drying and obtaining nitrogen-doped graphene-metal oxide nanocomposite material.