• 专利标题:   Molybdenum sulfide-tin sulfide/polyvinyl-propane sulfonyl imidazole bromide/polypyrrole/graphene oxide nano material for electrocatalytic modified electrode, is prepared using pyrrole, graphene oxide, potassium hydroxide, and thioacetamide.
  • 专利号:   CN113564635-A
  • 发明人:   SONG X, MA T, YANG H, MAO H
  • 专利权人:   UNIV LIAONING
  • 国际专利分类:   B82Y030/00, B82Y040/00, C25B001/27, C25B011/052, C25B011/095
  • 专利详细信息:   CN113564635-A 29 Oct 2021 C25B-011/095 202213 Chinese
  • 申请详细信息:   CN113564635-A CN11053958 09 Sep 2021
  • 优先权号:   CN11053958

▎ 摘  要

NOVELTY - Molybdenum sulfide-tin sulfide/poly 1-vinyl-3-propane sulfonyl imidazole bromide/polypyrrole/graphene oxide nano material material is prepared by polymerizing pyrrole on graphene oxide nanosheets, adding polypyrrole/graphene oxide nanosheets to N,N-dimethylformamide, ultrasonically dispersing, then adding chloropropylene and potassium hydroxide, stirring and reacting in oil bath at 60degrees Celsius for 24 hours, centrifuging, washing, vacuum drying, adding polypyrrole/graphene oxide-propylene nanosheets to absolute ethanol, ultrasonically dispersing, adding 1-vinyl-3-propane sulfonyl imidazole bromide and initiator, and transferring to 80degrees Celsius oil bath, refluxing under nitrogen protection for 6 hours, centrifuging, washing, and vacuum drying, dispersing poly 1-vinyl-3-propane sulfonyl imidazole bromide/polypyrrole/graphene oxide nanosheets in water, then adding ammonium-molybdenum-oxide tetrahydrate, tin chloride pentahydrate and thioacetamide, stirring evenly, and hydrothermally reacting. USE - Molybdenum sulfide-tin sulfide/poly 1-vinyl-3-propane sulfonyl imidazole bromide/polypyrrole/graphene oxide nano material used for forming NRR electrocatalytic modified electrode for electrocatalytic nitrogen reduction (all claimed). ADVANTAGE - The molybdenum sulfide-tin sulfide/poly 1-vinyl-3-propane sulfonyl imidazole bromide/polypyrrole/graphene oxide nano material has low price and high catalytic performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for use of a nitrogen-reduction rate (NRR) electrocatalytic modified electrode in electrocatalytic nitrogen reduction.