• 专利标题:   Preparing polyamide by putting caprolactam, laurolactam, distilled water and intermediate (A) into autoclave, vacuuming with nitrogen, reacting, filling with nitrogen protection, extracting, filtering to obtain polyamide material, and performing hydrosilylation reaction to generate intermediate.
  • 专利号:   CN113185690-A, CN113185690-B
  • 发明人:   DONG Y, WU H, ZHANG S, KONG H, LAI M
  • 专利权人:   DONGYING DALAI INTELLIGENT TECHNOLOGY CO LTD, YANTAI WANHUA POLYURETHANE SYNTHETIC MAT, DONGYING DALAI INTELLIGENT TECHNOLOGY CO
  • 国际专利分类:   C08G069/42
  • 专利详细信息:   CN113185690-A 30 Jul 2021 C08G-069/42 202175 Pages: 8 Chinese
  • 申请详细信息:   CN113185690-A CN10730705 30 Jun 2021
  • 优先权号:   CN10730705

▎ 摘  要

NOVELTY - Preparation method of high-fluidity polyamide, involves: putting 1500-1600 pts. wt. caprolactam, 400-500 pts. wt. laurolactam, 50-60 pts. wt. distilled water and 25-35 pts. wt. intermediate (A) into the autoclave, closing the feeding port, vacuuming and replacing the air in the reactor with high-purity nitrogen, operating it for 3 times, and finally keeping the pressure in the reactor at -0.09 to -0.06 MPa; heating the reactor to 200-300 degrees C, and reacting for 180-240 minutes; opening the exhaust valve, vacuuming and reacting for 120-180 minutes, filling with high-purity nitrogen protection, after standing for 100-120 minutes to equilibrate, extracting the obtained material in boiling water, filtering, washing and drying to obtain a polyamide material; and using 2-chloro-4,6-diallyltriazine, 3-methacrylamidodopamine, and hydrogen silsesquioxane as raw materials for the hydrosilylation reaction to generate the intermediate (A). USE - Preparation method of high-fluidity polyamide. ADVANTAGE - The polyamide has high-fluidity. The method prepares sulfonated graphene grafted polyamide in a high temperature and high pressure environment, which has high compatibility with the matrix polyamide resin, which is beneficial to the improvement of the mechanical properties and fluidity of the polyamide material. The polyamide having high-performance, uses a multi-branched polyamide material as the main matrix resin, and the molecules of the polyamide material have a smaller atomic spatial arrangement size and a symmetrical structure. The polyamide has the characteristics of no entanglement inside and outside the molecule and small intermolecular interaction. The melt viscosity of the polyamide is much lower than that of the linear polyamide with the same molecular weight. The polyamide has excellent fluidity broadens the application range of polyamide materials, shortens the processing cycle, and reduces system costs.