• 专利标题:   Preparing graphene thermally conductive anticorrosion integrated aqueous coating comprises e.g. reacting polyhydroxy-containing surface treatment agent with thermally conductive filler, polyamino-containing surface treatment agent, aqueous resin and leveling agent and sand grinding.
  • 专利号:   CN115991943-A
  • 发明人:   KANG Q, ZHANG M, WANG P, NING X
  • 专利权人:   HUNAN XIANGZHONG CHEM CO LTD, UNIV HUNAN HUMANITIES SCI TECHNOLOGY
  • 国际专利分类:   C09D005/08, C09D007/62
  • 专利详细信息:   CN115991943-A 21 Apr 2023 C09D-005/08 202343 Chinese
  • 申请详细信息:   CN115991943-A CN10192067 02 Mar 2023
  • 优先权号:   CN10192067

▎ 摘  要

NOVELTY - Preparing graphene thermally conductive anticorrosion integrated aqueous coating comprises e.g. (i) adding polyhydroxy-containing surface treatment agent into a mixed solution of ethanol and water, stirring, then adding thermally conductive filler to obtain thermally conductive filler with polyhydroxy groups on surface, (ii) adding worm-like graphene into absolute ethanol, adding thermally conductive filler prepared in step (i), adding diisocyanate and mixing to obtain composite material of worm-like graphene/thermally conductive filler, (iii) adding polyamino-containing surface treatment agent into mixed solution of ethanol and water, and adding composite material prepared in step (ii) to obtain thermally conductive filler with polyamino groups on the surface, and (iv) mixing thermally conductive filler prepared in step (iii), aqueous resin, deionized water, defoamer and leveling agent, sand grinding and adding crosslinking agent. USE - The method is useful in preparing graphene thermally conductive anticorrosion integrated aqueous coating. ADVANTAGE - The aqueous coating has excellent thermal conductivity in both horizontal and vertical directions, and excellent anti-corrosion performance at the same time. DETAILED DESCRIPTION - Preparing graphene thermally conductive anticorrosion integrated aqueous coating comprises (i) adding 1-5 pts. wt. polyhydroxy-containing surface treatment agent into a mixed solution of 95 pts. wt. ethanol and water, stirring at a speed of 100-1000 revolutions per minute for 5-10 minutes, then adding 10-1000 pts. wt. thermally conductive filler, and continue stirring for 10-60 minutes to obtain thermally conductive filler with polyhydroxy groups on surface, (ii) adding 1-5 pts. wt. worm-like graphene into 100 pts. wt. absolute ethanol, then adding 100-1000 pts. wt. the thermally conductive filler prepared in step (i), finally adding 1-5 pts. wt. diisocyanate and mixing at a high speed of 800-2000 revolutions per minute for 10-60 minutes, filtering and drying to obtain composite material of worm-like graphene/thermally conductive filler, (iii) adding 1-5 pts. wt. polyamino-containing surface treatment agent into the mixed solution of 95 pts. wt. ethanol and water, and then adding 10-1000 pts. wt. composite material prepared in step (ii), continue stirring at a speed of 100-1000 revolutions per minute for 5-10 minutes to obtain thermally conductive filler with polyamino groups on the surface, and (iv) mixing 1-80 pts. wt. thermally conductive filler prepared in step (iii), 1-99 pts. wt. aqueous resin, 0-50 pts. wt. deionized water, 0.1-1 pt. wt. anti-settling agent, 0.1-1 pt. wt. substrate wetting agent, 0.1-1 pt. wt. defoamer, and 0.1-1 pt. wt. leveling agent, stirring at a speed of 100-3000 revolutions per minute for 10-200 minutes, then sand grinding until the coating fineness is less than 40 μm, and then adding 1-10 pts. wt. crosslinking agent to obtain final product.