• 专利标题:   Adjusting and controlling orifice of porous carbon material, comprises e.g. slowly adding strong acid and strong oxidizing solid to porous carbon precursor in turn under ice-water bath conditions, stirring to obtain initial oxidation reaction solution, and slowly dropwise adding deionized water.
  • 专利号:   CN114408923-A
  • 发明人:   YANG Q, ZHANG Y, LI Q, ZHANG J, CHU Y, TAO Y
  • 专利权人:   UNIV TIANJIN
  • 国际专利分类:   C01B032/05, C01B032/354, H01M010/054, H01M004/583
  • 专利详细信息:   CN114408923-A 29 Apr 2022 C01B-032/354 202250 Chinese
  • 申请详细信息:   CN114408923-A CN10076899 24 Jan 2022
  • 优先权号:   CN10076899

▎ 摘  要

NOVELTY - Adjusting and controlling orifice of porous carbon material, comprises (i) slowly adding strong acid and strong oxidizing solid to porous carbon precursor in turn under ice-water bath conditions, and stirring uniformly to obtain initial oxidation reaction solution; (ii) increasing temperature of water bath to medium temperature, slowly dropwise adding deionized water to the initial oxidation reaction solution to obtain intermediate oxidation reaction solution; (iii) continuously increasing the temperature of the water bath to the first final temperature, stirring intermediate oxidation reaction solution, and obtaining the final oxidation reaction solution; and (iv) adding final oxidation reaction solution to post-treatment solution, filtering while hot, rinsing with dilute acid and deionized water, and drying to obtain oxidized porous carbon material. USE - The porous carbon material is used as cathode material for sodium ion battery. ADVANTAGE - The method: can achieves active control of the pore size of the porous carbon precursor, obtains a porous carbon material with reduced pore size (less than 0.4 nm) and maintains the intrinsic pore volume and rich pore structure. The porous carbon material: can significantly improves the sodium storage capacity and energy density, and accelerates the commercialization of sodium-ion batteries.