• 专利标题:   Preparation of flexible highly conductive graphene film, involves freezing oxidized graphene dispersion, and freeze-drying to obtain oxidized graphene sponge, and reducing oxidized graphene sponge with hydrazine reducing agent steam.
  • 专利号:   CN106986332-A, CN106986332-B
  • 发明人:   LI Y, CHEN R, HE X, XU F, LIN Z, PENG Q
  • 专利权人:   HARBIN HEZI NEW MATERIAL TECHNOLOGY CO
  • 国际专利分类:   C01B032/19
  • 专利详细信息:   CN106986332-A 28 Jul 2017 C01B-032/19 201764 Pages: 8 Chinese
  • 申请详细信息:   CN106986332-A CN10310070 04 May 2017
  • 优先权号:   CN10310070

▎ 摘  要

NOVELTY - The preparation method of flexible highly conductive graphene film involves (i) freezing oxidized graphene dispersion at -50 to -20 degrees C for 10-24 hours, and freeze-drying for 72-100 hours to obtain an oxidized graphene sponge, (ii) reducing oxidized graphene sponge with hydrazine reducing agent steam, (iii) heat treating in an inert gas protection atmosphere at 1000-5000 degrees C for 0.5-2 hours, (iv) vacuumizing to 10-400 Pa, and pressure treating at 30-500 MPa for 1 minute. USE - Preparation of flexible highly conductive graphene film (claimed). ADVANTAGE - The method enables the preparation of flexible highly conductive graphene film by simple process at low cost in a controlled manner with high productivity, conductivity, and density.