• 专利标题:   Preparing double polymer shell/nanoparticle core composite material having optically controlling thermal conductivity coefficient, comprises e.g. reacting graphene, 6-(4-((E)-2-phenyldiazen-1-yl)phenoxy)hexyl 2-methylprop-2-enoate, and butyl methacrylate and post-processing.
  • 专利号:   CN115340647-A
  • 发明人:   MIN X, SHE D, QIN W, HUANG C, WAN L, YUE W
  • 专利权人:   UNIV CHINA GEOSCIENCES BEIJING ZHENGZHOU, UNIV CHINA GEOSCIENCES BEIJING
  • 国际专利分类:   C08F220/18, C08F220/36, C08F292/00
  • 专利详细信息:   CN115340647-A 15 Nov 2022 C08F-292/00 202306 Chinese
  • 申请详细信息:   CN115340647-A CN10963782 11 Aug 2022
  • 优先权号:   CN10963782

▎ 摘  要

NOVELTY - Preparing double polymer shell/nanoparticle core composite material having optically controlling thermal conductivity coefficient, comprises (i) dissolving nanoparticles, monomer, butyl methacrylate, cyanoisopropyl dithiobenzoate and 2,2-azobisisobutyronitrile in anisole and configuring as a mixed solution, (ii) processing the mixed solution with four freeze-pump-thaw cycles and sealing under nitrogen, (iii) placing the mixed solution in an oil bath at a preset temperature to react for a preset time, (iv) polymerizing, and dropping the mixed solution containing the double polymer shell/nanoparticle core composite material into cold methanol for precipitation, (v) re-dispersing the precipitated product in dichloromethane, and dropping into cold methanol for secondary precipitation, and (vi) recrystallizing the precipitate three times in cold methanol, and drying in a vacuum oven at preset temperature for preset time to obtain the final product. USE - The method is useful for preparing double polymer shell/nanoparticle core composite materials. ADVANTAGE - The double polymer shell/nanoparticle core composite material is capable of adjusting and controlling thermal conductivity coefficient by changing the type of the radiation light.