• 专利标题:   Synthesizing tetramethyldiene triamine compound comprises e.g. heating amine and nitrile in palladium-rhodium graphene under hydrogen atmosphere, stirring, cooling, centrifuging and separating catalyst and reaction liquid and distilling.
  • 专利号:   CN111285772-A
  • 发明人:   WANG X, YANG Y, CUI Y
  • 专利权人:   JIAXING RUNBO CHEM TECHNOLOGY CO LTD
  • 国际专利分类:   B01J023/46, C07C209/00, C07C209/48, C07C211/14
  • 专利详细信息:   CN111285772-A 16 Jun 2020 C07C-209/48 202054 Pages: 6 Chinese
  • 申请详细信息:   CN111285772-A CN11319831 19 Dec 2019
  • 优先权号:   CN11319831

▎ 摘  要

NOVELTY - Synthesizing tetramethyldiene triamine compound (I) comprises adding amine and raw material nitrile into the reactor using palladium-rhodium graphene as catalyst, heating at 90 degrees C under hydrogen atmosphere of 3-8 MPa, stirring for 2-6 hours, cooling to room temperature, centrifuging and separating the catalyst and the reaction liquid, distilling the reaction solution under reduced pressure to obtain final product. USE - The method is useful for synthesizing tetramethyldiene triamine compound. ADVANTAGE - The method: has simple process, recyclable catalyst, reactants conversion rate of more than 95%, and selectivity of more than 90%. DETAILED DESCRIPTION - Synthesizing tetramethyldiene triamine compound of formula (I) comprises adding amine and raw material nitrile into the reactor using palladium-rhodium graphene (palladium/rhodium-CDG) as catalyst, heating at 90 degrees C under hydrogen atmosphere of 3-8 MPa, stirring for 2-6 hours, cooling to room temperature, centrifuging and separating the catalyst and the reaction liquid, distilling the reaction solution under reduced pressure to obtain final product. m, n = 1 or 2.