• 专利标题:   New carbonyl-based porous organic polymer useful as anode material for lithium ion battery.
  • 专利号:   CN115521454-A
  • 发明人:   WANG H, QU Y, ZHAO H, LIU R, WU Y, LIN W, XIE X
  • 专利权人:   UNIV TRANSFER PREPARATORY OFFICE MODERN ARTS SCI COLLEGE S
  • 国际专利分类:   C08G073/06, H01M010/0525, H01M004/60, H01M004/62
  • 专利详细信息:   CN115521454-A 27 Dec 2022 C08G-073/06 202315 Chinese
  • 申请详细信息:   CN115521454-A CN11145723 20 Sep 2022
  • 优先权号:   CN11145723

▎ 摘  要

NOVELTY - Carbonyl-based porous organic polymer i.e. (3,10,13,20,23,30-hexaazaheptacyclo20.8.0.0{2,11}.0{4,9}.0{12,21}.0{14,19}.0{24,29}triaconta-1(22),2(11),3,5,7,9,12(21),13,15,17,19,23,25,27,29-pentadecaene) polymer compound (I) is new.(I) comprise 6,16,26-tribromo-3,10,13,20,23,30-hexaazaheptacyclo20.8.0.0{2,11}.0{4,9}.0{12,21}.0{14,19}.0{24,29}triaconta-1(22),2(11),3,5,7,9,12(21),13,15,17,19,23,25,27,29-pentadecaene as building monomer and carbonyl compound as connecting group. USE - (I) is useful as anode material for preparing lithium-ion battery (claimed) in various environments. ADVANTAGE - (I): is a 2D planar polymer, and has high specific surface area and open pore structure are more conducive to ion diffusion, multiple redox points and lowest unoccupied molecular orbital energy level, excellent thermal stability, and its thermal decomposition temperature of 310-400℃, which is beneficial to manufacture and operation of lithium-ion batteries in various environments and combines with graphene oxide, and thus improves charge transport kinetics, improves cycle stability and rate performance of battery. DETAILED DESCRIPTION - Carbonyl-based porous organic polymer i.e. (3,10,13,20,23,30-hexaazaheptacyclo20.8.0.0{2,11}.0{4,9}.0{12,21}.0{14,19}.0{24,29}triaconta-1(22),2(11),3,5,7,9,12(21),13,15,17,19,23,25,27,29-pentadecaene) polymer compound of formula (I) is new. The porous organic polymer uses 2,8,14-tribromodiquinoxaline2,3-a:2',3'-cphenazine as a building monomer and a carbonyl compound as a linking group. R = linking group; and n = positive integer. INDEPENDENT CLAIMS are also included for: 1. preparation of (I); and 2. use method of (I), comprising compounding (I) with graphene oxide, which is used as anode material of lithium ion battery.