• 专利标题:   Preparation of encapsulated porous strong acid catalyst comprises mixing transition metal salt and organic ligand in polar solvents, adding arylsulfonic acid and co-agent salt, reacting, adding graphene powder, crystallizing, and drying.
  • 专利号:   CN110787839-A
  • 发明人:   JIN S, HU J, LIU Y, ZHAO X, JIANG Y, WANG L, SONG Y, FANG Z, JIANG Z, LI Y
  • 专利权人:   WANHUA CHEM GROUP CO LTD
  • 国际专利分类:   B01J031/22, B01J035/10, C07C067/08, C07C069/40, C07C069/42, C07C069/44
  • 专利详细信息:   CN110787839-A 14 Feb 2020 B01J-031/22 202018 Pages: 12 Chinese
  • 申请详细信息:   CN110787839-A CN11006861 22 Oct 2019
  • 优先权号:   CN11006861

▎ 摘  要

NOVELTY - Preparation of encapsulated porous strong acid catalyst comprises dissolving transition metal salt in a polar inert solvent as 5-30 wt.% first solution, dissolving organic ligand in polar inert solvent as 10-50 wt.% second solution, dissolving arylsulfonic acid and co-agent salt in polar inert solvent as 10-30 wt.% third solution; mixing first and second solutions and reacting for 1-3 hours; adding third solution, adjust pH to 7.5-9.0, crystallizing at high temperature, and cooling to room temperature; adding graphene powder and templating agent, mixing, and crystallizing at high temperature; and filtering, washing with ethanol, drying at 100-120 degrees C for 8-12 hours, and shaping. USE - The method is used for preparing encapsulated porous strong acid catalyst. ADVANTAGE - The catalyst has high activity and dibasic selectivity.