• 专利标题:   Manufacturing method for making scaffold-free three-dimensional porous electrode involves depositing second layer of electrochemically active material onto underside of graphene coating to form three-dimensional porous electrode.
  • 专利号:   US2016351886-A1, US10062904-B2
  • 发明人:   BRAUN P V, LIU J
  • 专利权人:   UNIV ILLINOIS FOUND, UNIV ILLINOIS FOUND
  • 国际专利分类:   H01M010/0525, H01M004/04, H01M004/131, H01M004/133, H01M004/134, H01M004/38, H01M004/48, H01M010/00, H01M004/1391, H01M004/1393, H01M004/1395, H01M004/485, H01M004/505, H01M004/525, H01M004/58, H01M004/02
  • 专利详细信息:   US2016351886-A1 01 Dec 2016 H01M-004/04 201680 Pages: 18 English
  • 申请详细信息:   US2016351886-A1 US163003 24 May 2016
  • 优先权号:   US166602P, US163003

▎ 摘  要

NOVELTY - The manufacturing method involves depositing one or more monolayers of graphene (210) onto a porous scaffold to form a graphene coating (212) on the porous scaffold. A first layer of electrochemically active material (214) is deposited onto the graphene coating. The porous scaffold is removed to expose the underside of the graphene coating. A second layer of electrochemically active material (216) is deposited onto the underside of the graphene coating to form a three-dimensional (3D) porous electrode (220). USE - Manufacturing method for making scaffold-free 3D porous electrode (claimed). ADVANTAGE - Obtains scaffold-free porous electrode that combines high volume fraction of active materials with good electrical conductivity and low mass of graphene to exhibit high capacity, good cycle stability and fast charge-discharge kinetics. Optimizes thickness of each active material layer to maximize volume of electrochemically active material for given scaffold geometry. Obtains mechanically-robust strucutre that prevents loss of active nanomaterials and collapse during long-term cycling. Improves anode electronic conductivity. DESCRIPTION OF DRAWING(S) - The drawing shows the perspective view of a 3D porous electrode during fabrication process. Monolayers of graphene (210) Graphene coating (212) First layer of electrochemically active material (214) Second layer of electrochemically active material (216) 3D porous electrode (220)