• 专利标题:   Anode active material particle used e.g. in lithium battery comprises internal pores having pore volume and pore wall surfaces, and solid portion having solid volume and are infiltrated with graphene material that partially or fully covers internal pore wall surfaces.
  • 专利号:   US2022069281-A1
  • 发明人:   JANG B Z, SU Y, ZHAMU A, CHAI S, MISHRA K
  • 专利权人:   GLOBAL GRAPHENE GROUP INC
  • 国际专利分类:   H01M010/0525, H01M004/04, H01M004/131, H01M004/133, H01M004/134, H01M004/36, H01M004/60
  • 专利详细信息:   US2022069281-A1 03 Mar 2022 H01M-004/133 202224 English
  • 申请详细信息:   US2022069281-A1 US005915 28 Aug 2020
  • 优先权号:   US005915

▎ 摘  要

NOVELTY - Anode active material particle comprises internal pores, having a pore volume of Vp and pore wall surfaces, and a solid portion having a solid volume Va, where the volume ratio of Vp/Va is 0.1/1-10/1 and the pores have pore sizes of 2-10 microm, and are infiltrated with a graphene material that partially or fully covers the internal pore wall surfaces. USE - The particle is useful in a lithium battery, lithium metal secondary battery, lithium-sulfur battery, lithium-air battery or lithium-selenium battery (all claimed). ADVANTAGE - The particle: enables a lithium-ion battery to exhibit a high cycle life, high reversible capacity, low irreversible capacity, small particle sizes (for high-rate capacity), and compatibility with commonly used electrolytes; reduces battery capacity decay rate and dramatically increased charge/discharge cycle numbers; increases first-cycle efficiency and the Coulombic efficiencies of subsequent cycles; prevents direct contact between liquid electrolyte and the internal surfaces of the porous anode material particle; and prevents formation of solid-electrolyte interface layer on these internal surfaces. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) a mass of anode particles containing the anode particle; (2) a battery anode containing the particle or multiple particles; (3) a battery containing the battery anode; and (4) producing multiple particles. DESCRIPTION OF DRAWING(S) - The figure shows a schematic view of depositing a graphene material on internal pore wall surfaces of a porous anode active material particle.