• 专利标题:   Depositing graphene or graphene oxide onto substrate from gaseous source of carbon precursor involves using plasma-enhanced chemical vapor deposition method, where carbon precursor consists of ethylene and the process is carried out in absence of carrier gas.
  • 专利号:   WO2023079018-A1
  • 发明人:   JOUIAD M, EL MARSSI M, LEJEUNE M
  • 专利权人:   UNIV PICARDIE VERNE JULES
  • 国际专利分类:   B01J019/08, B01J019/12, B01J019/22, B01J019/28, B82Y030/00, B82Y040/00, C01B032/186, C01B032/198, C23C016/02, C23C016/26, C23C016/28, C23C016/455, C23C016/50, C23C016/505, C23C016/56, H01J037/32, H01L021/02
  • 专利详细信息:   WO2023079018-A1 11 May 2023 C23C-016/26 202340 Pages: 22 English
  • 申请详细信息:   WO2023079018-A1 WOEP080712 03 Nov 2022
  • 优先权号:   EP306551

▎ 摘  要

NOVELTY - Process for depositing graphene or graphene oxide onto a substrate from a gaseous source of at least one carbon precursor, involves using a plasma-enhanced chemical vapor deposition method, where the carbon precursor consists of ethylene and in that the process is carried out at 18-40° C and in the absence of carrier gas. USE - The process is useful for depositing graphene or graphene oxide onto a substrate from a gaseous source of at least one carbon precursor. ADVANTAGE - The process uses ethylene, which is a non-harmful gas, and is conducted at a temperature around room temperature, and consumes less energy, and is suitable directly applied to a diversity of substrates, and allows omitting any prior step of treating the substrate, for instance by cleaning with a plasma, and grows high quality, and large area graphene, for instance products of about 15x 15 cm2or even 100 cm2or 200 cm2, and the device is economical, and does not require a furnace. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a device suitable for the production of graphene or graphene oxide on a substrate, comprising a container comprising a gaseous source of carbon precursors consisting of ethylene, a plasma reactor comprising a plasma chamber comprising a sample stand suitable for holding a substrate, and a plasma generator comprising a power source and connected to, or including, the plasma chamber, and a pumping system suitable for putting the plasma chamber under vacuum and in fluid communication with the plasma chamber, and for feeding ethylene from the container into the plasma chamber.