• 专利标题:   Preparing high heat-resistant liquid crystal polymer resin, by transesterifying prepolymers obtained by melt polycondensation of p-hydroxybenzoic acid, hydroquinone, 6-hydroxy-2-naphthoic acid and terephthalic acid, and solid-state polymerizing obtained liquid crystal polymer and inorganic filler.
  • 专利号:   CN113717501-A
  • 发明人:   XU L, YU R, ZHANG D
  • 专利权人:   NINGXIA QINGYAN POLYMER NEW MATERIAL CO
  • 国际专利分类:   C08G063/60, C08K003/04, C08K003/36, C08L067/00, C09K019/38
  • 专利详细信息:   CN113717501-A 30 Nov 2021 C08L-067/00 202227 Chinese
  • 申请详细信息:   CN113717501-A CN11051843 08 Sep 2021
  • 优先权号:   CN11051843

▎ 摘  要

NOVELTY - Preparing high heat-resistant liquid crystal polymer (LCP) resin involves: (1) preparing a prepolymer (A) by melt polycondensation of p-hydroxybenzoic acid and hydroquinone; (2) preparing a prepolymer (B) by melt polycondensation of 6-hydroxy-2-naphthoic acid and terephthalic acid; (3) transesterifying the prepolymers (A) and (B) to obtain LCP; and (4) solid-state polymerizing the LCP and an inorganic filler. USE - The method is useful for preparing high heat-resistant LCP resin (claimed). ADVANTAGE - The method provides high heat-resistant LCP resin, which has reduced viscosity through solid-state polymerization with inorganic filler, and improved mechanical strength. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the high heat-resistant LCP resin, which has a melting point of 300-380degrees Celsius, a thermal decomposition temperature of 450-510degrees Celsius, and a tensile strength of greater than 60 MPa.