• 专利标题:   Vertical graphene/titanium/oxygen/sulfur carbon composite material useful as cathode material for lithium ion battery, comprises graphene nanosheet intertwined on substrate, and titanium niobium oxide coated on graphene nanosheet.
  • 专利号:   CN108649190-A
  • 发明人:   XIA X, CHEN C, DENG C, TU J, WANG X
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   H01M004/36, H01M004/583, H01M004/48, H01M010/0525, B82Y030/00
  • 专利详细信息:   CN108649190-A 12 Oct 2018 H01M-004/36 201880 Pages: 9 Chinese
  • 申请详细信息:   CN108649190-A CN10263754 28 Mar 2018
  • 优先权号:   CN10263754

▎ 摘  要

NOVELTY - A vertical graphene/titanium/oxygen/sulfur carbon composite material comprises graphene nanosheet grown vertically and intertwined on a substrate, titanium niobium oxide coated on the graphene nanosheet, vertical graphene/titanium niobium oxide nanosheet and sulfur-doped carbon layer coated on the vertical graphene/titanium niobium oxide nanosheet. USE - The vertical graphene/titanium/oxygen/sulfur carbon composite material is useful as cathode material for lithium ion battery (claimed) and in electronic equipment such as electric vehicles and hybrid vehicles. ADVANTAGE - The vertical graphene/titanium/oxygen/sulfur carbon composite material has three-dimensional porous array structure and excellent high-rate performance and coulombic efficiency, and improves the energy density/power density and cycle stability of lithium ion battery. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation method of vertical graphene/titanium/oxygen/sulfur carbon composite material, which involves depositing graphene array on the carbon cloth by plasma enhanced chemical vapor deposition method to obtain vertical graphene nanosheet, drying the vertical graphene nanosheet carrying out solvothermal reaction using vertical graphene nanosheet as growth substrate, isopropyl titanate and antimony pentachloride as precursor, washing, drying, and heat treating to obtain vertical graphene/titanium niobium oxide nanosheet, and dissolving 3,4-ethylenedioxythiophene and lithium perchlorate in acetonitrile, depositing poly(3,4-ethylenedioxythiophene) on the prepared vertical graphene/titanium niobium oxide nanosheet by constant current anodic deposition and then calcining.