• 专利标题:   Color nanocomposite comprises amino-functionalized surface of graphene oxide and carboxyl-modified manganese-doped nanocrystals, where the carboxyl-modified manganese-doped nanocrystals comprise covalent coupling and mercapto group.
  • 专利号:   CN103525413-A, CN103525413-B
  • 发明人:   WANG S, ZHANG K
  • 专利权人:   CHINESE ACAD SCI HEFEI INST PHYS SCI
  • 国际专利分类:   C09K011/65, G01N021/64
  • 专利详细信息:   CN103525413-A 22 Jan 2014 C09K-011/65 201423 Pages: 10 Chinese
  • 申请详细信息:   CN103525413-A CN10486786 17 Oct 2013
  • 优先权号:   CN10486786

▎ 摘  要

NOVELTY - Color nanocomposite comprises amino-functionalized surface of graphene oxide and carboxyl-modified manganese-doped nanocrystals, where the carboxyl-modified manganese-doped nanocrystals comprise covalent coupling, mercapto group and a carboxyl functional group-modified compound. USE - Color nanocomposite. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing color nanocomposite, which involves: (A) preparing amino-functionalized surface of graphene oxide by refluxing thionyl chloride with graphene oxide under the protection of the inert gas; (B) removing the unreacted substance after washing; (C) vacuum drying to obtain the product; (D) processing the product under the protection of nitrogen for 72 hours; (E) cooling the product to room temperature; (F) vacuum drying and removing the solvent to obtain the amino-functionalized surface of graphene oxide; (G) dissolving nano zinc in deionized water; (H) dissolving manganese acetate in the solution; (I) introducing nitrogen gas to the solution; (J) adding the sodium sulfide to the solution; (K) refluxing and strongly stirring the mixture for 5 hours; (L) cooling and centrifuging the mixture to obtain manganese-doped zinc sulfide nano-crystals; (M) ultrasonically dispersing nano-crystals in water for further use; (N) dissolving mercaptoacetic acid or mercaptopropionic acid in the solution; (O) stirring the solution for 12-48 hours; and (P) stirring the mixture for 0.5-5 hoursto obtain the desired product.