• 专利标题:   Composite adsorption material for adsorbing e.g. organic material in aqueous system, is formed by filling holes of porous spherical crosslinked resin with modified graphene oxide obtained by modifying graphene oxide with modifying agent.
  • 专利号:   CN106799215-A
  • 发明人:   WANG S, ZHENG R, WU X, ZHONG H, CAO Z
  • 专利权人:   UNIV CENT SOUTH
  • 国际专利分类:   B01J020/26, B01J020/30, C02F001/28, C02F101/20, C02F101/22, C02F101/34, C08F126/10, C08F212/08, C08F212/36, C08F220/14, C08F226/10
  • 专利详细信息:   CN106799215-A 06 Jun 2017 B01J-020/26 201756 Pages: 15 Chinese
  • 申请详细信息:   CN106799215-A CN10067396 06 Feb 2017
  • 优先权号:   CN10067396

▎ 摘  要

NOVELTY - A composite adsorption material is formed by filling holes of porous spherical crosslinked resin with graphene oxide and/or modified graphene oxide. The modified graphene oxide is obtained by chemically modifying graphene oxide with modifying agent(s) chosen from chitosan, N-alkylamide-based carboxylic acid, N-alkylamide-based hydroxamic acid, ethylenediamine, diethylenetriamine, triethylenetetramine and tetraethylenepentamine. USE - Composite adsorption material is used for adsorbing organic material e.g. methylene blue, rhodamine B, active black 5, azure, phenol, bisphenol A, salicylic acid and p-toluenesulfonic acid, and heavy metal ion e.g. manganese ion, copper ion, lead ion, zinc ion, chromium ion, cadmium ion, mercury ion, arsenic ion, cobalt ion and nickel ion, in aqueous system (all claimed). ADVANTAGE - The composite adsorption material has excellent adsorption performance, and can be prepared by simple process under easily controllable reaction conditions, and is easy to use. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the composite adsorption material, which involves dispersing a polymeric monomer, a crosslinking agent, a pore-forming agent, an initiator and modified graphene oxide and/or graphene oxide, mixing resultant product with solution containing a dispersant, heating, subjecting resultant product to suspension polymerization, and curing, and optionally crosslinking resultant product in presence of a Lewis acid catalyst at 80-100 degrees C.