• 专利标题:   Method for preparing sodium titanate/graphene composite cathode material for sodium ion battery, involves dispersing graphene oxide in anhydrous ethanol, and adding surface modifier followed by mixing with titanium and sodium compounds.
  • 专利号:   CN104600271-A, CN104600271-B
  • 发明人:   DONG W, LI H, LI S, SHEN D, WANG X, ZHANG Q, YANG S
  • 专利权人:   UNIV LIAONING TECHNICAL
  • 国际专利分类:   H01M004/36
  • 专利详细信息:   CN104600271-A 06 May 2015 H01M-004/36 201553 Pages: 8 Chinese
  • 申请详细信息:   CN104600271-A CN10056054 03 Feb 2015
  • 优先权号:   CN10056054

▎ 摘  要

NOVELTY - A sodium titanate/graphene composite cathode material preparing method involves dispersing graphene oxide in anhydrous ethanol, and adding a surface modifier at 30-60 degrees C to obtain a graphene oxide solution. The graphene oxide solution is mixed with titanium-containing compound and sodium compound, and reacted for 20-60 minutes. The reaction mixture is filtered and dried to obtain a composite precursor. Spray-drying granules and a binder are mixed with the precursor to obtain a spherical composite precursor. The precursor is sintered in an inert atmosphere to obtain the finished product. USE - Method for preparing a sodium titanate/graphene composite cathode material that is utilized for a sodium ion battery. ADVANTAGE - The method enables preparing the composite cathode material with high sodium storage capacity, long cycle life, high-current discharge performance and compaction density. DETAILED DESCRIPTION - A sodium titanate/graphene composite cathode material preparing method involves dispersing graphene oxide in anhydrous ethanol, and adding an appropriate amount of surface modifier at 30-60 degrees C under constant temperature sonication for 30-240 minutes to obtain a graphene oxide solution. The graphene oxide solution is mixed with titanium-containing compound and sodium compound, and reacted for 20-60 minutes. The reaction mixture is filtered and dried to obtain a composite precursor. Spray-drying granules and a binder are mixed with the precursor to obtain a spherical composite precursor. The precursor is sintered in an inert atmosphere to obtain the finished product.